After L-cystine is obtained from corn starch fermentation, L-cystine [HCl]→[electrolytic reduction] L-cysteine hydrochloride [decolorization, concentration, crystallization]→ L-cysteine hydrochloride crystal decolorization, concentration, crystallization electrolysis is completed, cut off the power supply, and add 10g/L(1%) activated carbon according to the dosage. Heat to 70 ° C and keep warm for half an hour. Filter for filtrate. And concentrate it under reduced pressure until there is crystallization, stir so that the crystallization is completely precipitated, filter the crystallization, wash with 95% ethanol, vacuum drying below 60℃, to obtain L-cysteine hydrochloride without crystal water.